Laboratory of spin physics and spin chemistry

The Theory More...

Pulse EPR spectroscopy

The research is aimed at the development of nanometrology, the implementation of quantum computation, and the study of the spin dynamics of radicals, transition metal ions and molecular heterospin systems. More...

The research is aimed at the development of strategies to create new molecular magnetic materials including single molecular magnets.

Time-resolved EPR spectroscopy of spin-polarized states More...

NMR- spectroscopy

An Avance 400 multinuclear pulsed NMR spectrometer (Bruker) makes it possible to obtain 1D and 2D NMR spectra using the ¹H decoupling and to measure the relaxation times and self-diffusion coefficients.

The research is aimed at the implementation of quantum algorithms, the study of particle diffusion in inhomogeneous structures, structural and dynamic properties of proteins and novel compounds including liquid crystals.

Kazan State University, Kazan
Kazan State Technological University, Kazan
Institute of Solid State Chemistry of the Siberian Branch of RAS, Novosibirsk
A.N. Frumkin Institute of Physical chemistry and Electrochemistry RAS
Karlsruhe Institute of Technology (KIT), Germany.      

2016

1. K. M. Salikhov, M. M. Bakirov, R. T. Galeev Detailed Analysis of Manifestations of the Spin Coherence Transfer in EPR Spectra of 14N Nitroxide Free Radicals in Non-Viscous Liquids. , Appl Magn Reson. 47, 1095–1122 (2016)

2. Yoeun S., Sukhanov A., Han O. Binding of Imidazole Stabilizes Low‐spin State of Heme Iron in Dual‐Substrate‐Specific Rice Allene Oxide Synthase‐1 //Bulletin of the Korean Chemical Society. – 2015. – Т. 36. – №. 8. 

3. Yoeun S., Sukhanov A., Han O. Separation of enzymatic functions and variation of spin state of rice allene oxide synthase-1 by mutation of Phe-92 and Pro-430 //Bioorganic Chemistry. – 2016. – Т. 68. – С. 9-14. 

4. A. A. Sukhanov, L.I. Savostina, V. K. Voronkova, E. A. Mikhalitsyna, V. S. Tyurin. Time-Resolved and Pulse EPR Study of Conjuncted Porphyrin Trimer. Appl. Magn. Reson., 47(11), 1295-1304 (2016)

5. Electron Transfer Pathways in a Tetrathiafulvalene-Aluminum (III) Porphyrin-Free-Base Porphyrin Triad Studied Using Electron Spin Polarization. Yu. E. Kandrashkin, P. K. Poddutoori, and A. van der Est Applied Magnetic Resonance 47 (5), 511-526, 2016

6. R.M. Eremina, T.P. Gavrilova, I.V. Yatsyk, R.B. Zaripov, A.A. Sukhanov, V.A. Shustov, N.M. Lyadov, V.I. Chichkov, N.V. Andreev/ Magnetic Resonance Investigations of h-YbMnO3/ Appl. Magn. Reson. –2016. - V.47. – P. 869-8792

7. .A.I. Kokorin, R.B. Zaripov, O.I. Gromov, A.A. Sukhanov, T. Kálai, É. Lamperth, K. Hideg / Spin Density Distribution in a Nitroxide Biradical Containing 13C-Enriched Acetylene Groups in the Bridge: DFT Calculations and EPR Investigation/ Appl. Magn. Res.- 2016.- P.1057-1067

8. Kokorin A. I., Sukhanov, A. A., Gromov, O. I., Arakelyan, V. M., Aroutiounian, V. M., & Voronkova, V. K.  EPR Study of TiO2 (Rutile) Doped with Vanadium //Applied Magnetic Resonance. – 2016. – Т. 47. – №. 5. – С. 479-485.

9. Andrianov V.V., Pashkevich S.G., Yafarova G.G., Denisov A.A., Iyudin V.S., Bogodvid T.Kh., Dosina M.O., Kulchitsky V.A.,.Gainutdinov Kh.L Changes of Nitric Oxide Content in the Rat Hippocampus, Heart and Liver in Acute Phase of Ischemia. Applied Magnetic Resonance. 2016, 47 (9), 965-976

10. Alekseev A.V., Gumarov G.G., Bakirov M.M., Petukhov V.Y., Nuzhdin V.I. Ferromagnetic resonance investigation of magnetic anisotropy of ion-synthesized iron-silicide thin films. Journal Of Surface Investigation: X-Ray, Synchrotron And Neutron Techniques , V. 10, №3, 2016, P608-611.

2015

1. К.M. Salikhov, I.T. Khairuzhdinov. Four-Pulse ELDOR Theory of the Spin Label Pairs. Extended to Overlapping EPR Spectra and to Overlapping Pump and Observer Excitation Bands. Appl. Magn, Reson. 46, 67-83 (2015) 

2. Mohammad A. Abdulmalic, Azar Aliabadi, Andreas Petr, Yulia Krupskaya, Vladislav Kataev, Bernd Buchner, Ruslan Zaripov, Evgeniya Vavilova, Violeta Voronkova, Kev Salikhov, Torsten Hahn, Jens Kortus, Francois Eya’ane Meva, Dieter Schaarschmidt and Tobias Ruffer. Magnetic superexchange interactions: trinuclear bis(oxamidato) versus bis(oxamato) type complexes. Dalton Trans., 44, 8062-8079 (2015)

3. A. A. Sukhanov, K. B. Konov, K. M. Salikhov,V. K. Voronkova, E. A. Mikhalitsyna, V. S. Tyurin. Time-Resolved Continuous-Wave and Pulse EPR Investigation of Photoinduced States of Zinc Porphyrin Linked with an Ethylenediamine Copper Complex. Appl. Magn. Reson.,46, 1190-1220( 2015), DOI 10.1007/s00723-015-0705-0

4. Electron Spin Density on the N‑Donor Atoms of Cu(II)−(Bis)oxamidato Complexes As Probed by a Pulse ELDOR Detected by NMR/A. Aliabadi, R. Zaripov, K.Salikhov, V. Voronkova, E.Vavilova, M. A. Abdulmalic, T. Ruffer, B.Buchner, and V. Kataev// J.Phys.Chem.B 2015. DOI: 10.1021/acs.jpcb.5b03987

5. Membrane−Sugar Interactions Probed by Pulsed Electron Paramagnetic Resonance of Spin Labels. K. B. Konov, D. V. Leonov, Nikolay P. Isaev, Kirill Yu. Fedotov,V. K. Voronkova, and Sergei A. Dzuba/ J.Phys.Chem.B, 2015, DOI: 10.1021/acs.jpcb.5b06864

6. N.M. Selivanova, A.B. Konov, K.A. Romanova, A.T. Gubaidullin, Yu.G. Galyametdinov. Lyotropic La-containing lamellar liquid crystals: phase behaviour, thermal and structural properties. Soft Matter, 2015. v. 11. pp. 7809-7816 .

7. Ivanshin, V. A., Litvinova, T. O., Gimranova, K., Sukhanov, A. A., Jia, S., Bud'ko, S. L., & Canfield, P. C. (2015, March). Dual nature of 3d electrons in YbT2Zn20 (T= Co; Fe) evidenced by electron spin resonance. In Journal of Physics: Conference Series (Vol. 592, No. 1, p. 012084). IOP Publishing. 

8. Андрианов В.В., Гайнутдинов Х.Л. Модель пластичной нейронной сети оборонительного поведения виноградной улитки на основе спайковых формальных нейронов с формальной активностью. Нейрокомпьютеры: разработка, применение. 2015. № 4. С. 15-17.

9. Andrianov V.V., Bogodvid T.Kh., Deryabina I.B., Golovchenko A.N., Muranova L.N., Tagirova R.R., Vinarskaya A.Kh., Gainutdinov Kh.L. Modulation of defensive reflex conditioning in snails by serotonin. Frontiers in Behavioral Neuroscience, 2015, v.9, Article 279, p. 1-12.

2014

1. A.B. Konov, K.M. Salikhov, E.I. Vavilova, B.Z. Rameev. Multiparameter NMR Identification of Liquid Substances. In: Magnetic Resonance Detection of Explosives and Illicit Materials. Ed. By T. Apih, B. Rameev, G. Mozzhukhin, J. Barras. NATO Science for Peace and Security Series-B. Physics and Biophysics, Springer, pp. 111-122, 2014

2. K.M. Salikhov, I. Khairuzhdinov, R.B. Zaripov. PELDOR theory revisited. Appl. Magn. Reson. 45, 573-619 (2014)

3. K.M. Salikhov, A.E. Mambetov, M.M Bakirov, R.T. Galeev, I.T. Khairuzhdinov, R.B. Zaripov, B. Bales. Spin exchange between charged paramagnetic particles in dilute solutions. . Appl. Magn. Reson. 45, 911-940 (2014)

4. D.V. Lapaev, V.G. Nikiforov, G.M. Safiullin, V.S. Lobkov, K.M. Salikhov, A.I. Knyazev, Yu.G. Galyametdinov. Laser control and temperature switching of luminescence intensity in photostable transparent film based on terbium (III) β-diketonate complex. Optical materials 37, 593-597 (2014)

5. V.F. Tarasov, R.B. Zaripov, N.K. Solovarov, A.A. Sukhanov E.V. Zharikov. Combined magneto-electric spin resonance of impurity Ho ions in synthetic forsterite. Appl. Magn. Reson. v.45, no.2, p.239-253 (2014),

6. K. B. Konov N. P. Isaev S. A. Dzuba «Low-Temperature Molecular Motions in Phospholipid Bilayers in Presence of Glycerol as Studied by Spin-Echo EPR of Spin Labels» - Applied Magnetic Resonance (2014) 45:1117–1126

7. Konstantin B. Konov, Nikolay P. Isaev, and Sergei Andreevich Dzuba «Low-Temperature Molecular Motions in Lipid Bilayers in Presence of Sugars: Insights into Cryoprotective Mechanisms» J. Phys. Chem. B 2014, 118 (43), pp 12478–12485

8. K.I.Gerasimov,S.A.Moiseev,V.I.Morozov,R.B.Zaripov /Room-temperature storage of electromagnetic pulses on a high-finesse natural spin-frequency comb/ Phys.Rev.A – 2014 – V.90 – P. 042306_1-6

9. Shtyrlin, V.G. The C–H bond activation in 1-ethyl-3-methylimidazolium acetate–copper(II) acetate–water–air (dioxygen) systems/ V. G. Shtyrlin, N. Yu. Serov, D. R. Islamov, A. L. Konkin, M. S. Bukharov, O.I. Gnezdilov, D. B. Krivolapov, O. N. Kataeva, G. A. Nazmutdinova and F. Wendler|// Dalton Trans.- 2014. V.43. – P.799-805.

10. Yuri E. Kandrashkin • Art van der Est. Orientation Information from the Dipolar Interaction Between a Complex in the Excited Quartet State and a Doublet Spin Label. Appl. Magn. Reson. v.45, no.3, p.217-237 (2014)

1. Mingalieva L.V., Ciornea V., Voronkova V.K., et al.: Synthesis, structural characterization, magnetic and EPR studies of heterometallic Cu2Cr2 and Cu2Ga2 complexes. Polyhedron 45, no. 1, 238-244 (2012)

2. Zakharova L.Ya., Gaysin N.K., Gnezdilov O.I., Bashirov F.I., Kashpov R.R., Zhiltsova E.P., Pashirova T.N., Lukashenko S.S.: Micellization of alkylated 1,4-diazabicyclo[2.2.2]octana by nuclear magnetic resonance technique using gradient of static magnetic field. J. Mol. Liq. 167, 89-93 (2012)

3. Khasiyatullina N.R., Mironov V.F., Gnezdilov O.I.:Reaction of 6-bromo-2-hydroxy-4- tributylphosphonium naphthyl-1-ate with chlorobis(phenylenedioxy)spirophosphoranes. Rus. J. Gen. Chem. 82, no. 5, 939-941 (2012)

4. Iyudin V.S., Kandrashkin Yu.E., Voronkova V.K., Tyurin V.S., Kirichenko E.N.: Time-resolved EPR spectra of photoexcited copper porphyrin. Appl. Magn. Reson. 40, no. 1, 75-89 (2011)

5. Zaripov R.B., Dzhabarov V.I., Knyazev A.A., Galyametdinov Yu.G., Kulik L.V.: Usе of additional fast-relaxing paramagnetic species for improvement of RIDME performance. Appl. Magn. Reson. 40, no. 1, 11-19 (2011)

6. Krupskaya Y., Zaripov R., Vavilova E., Miluykov V., Bezkishko I., Krivolapov D., Kataeva O., Sinyashin O., Hey-Hawkins E., Voronkova V., Salikhov K., Kataev V., Büchner B.: Electron spin coherence in antiferromagnetically coupled binuclear Mn complexes. Phys. Rev. B 84, 0924021-0924024 (2011)

7. Matukhin V.L., Ulanov V.A., Sukhanov A.A., Safonov A.N., Shmidt S.V., Aminov T.G.,. Shabunina G.G.: Investigation of CuGaTe2 semiconductor compounds doped with Mn by the EPR method. Rus. Phys. J. 54, no. 3, 283-287 (2011)

8. Ivanshin V.A., Litvinova T.O., Sukhanov A.A., Ivanshin N.A., Endeward B.: Hybridized electronic states in dense intermetallics as studied by ESR. Solid State Phenomena 170, 170-173 (2011)

9. Strukova G.K., Strukov G.V., Bozhko S.I., Kabanov Yu.P., Shmytko I.M., Mazilkin A.A., Sobolev N.A., Zhiteytsev E.R., Sukhanov A.A., Voronkova V.K., Tagirov L.R.: Structure and magnetic properties of nanostructured Pd-Fe thin films produced by pulse electrodeposition. J. Nanosci. Nanotechnol. 11, 8907-8911 (2011)

10. Gnezdilov O.I., Zuev Yu.F., Zueva O.S., Patarikina K.S., Us’yarov O.G.: Self-diffusion of ionic surfactants and counterions in premicellar and micellar solutions of sodium, lithium and cesium dodecyl sulfates as studied by NMR-diffusometry. Appl. Magn. Reson. 40, no. 1, 91-103 (2011)

11. Zaripova A.R., Spiridonova R.R., Gnezdilov O.I., Rizvanov I.K., Litvinov I.A., Gubaydulin A.T., Samuilov Y.D.: Structure of the product of interaction of N-vinylcaprolactam with 3-chlorophenylisocyanate. J. Struct. Chem. 52, no. 1, 180-185 (2011)

12. Faizullin D.A., Vylegzhanina N.N., Gnezdilov O.I., Salnikov V.V., Galukhin A.V., Stoikov I.I., Antipin I.S., Zuev Yu.F.: Influence of nature of functional groups on interaction of tetrasubstituted at lower rim p-tert-butyl thiacalix[4]arenas in 1,3-alternate configuration with model lipid membranes. Appl. Magn. Reson. 40, no. 2, 231-243 (2011)

13. Volkov M., Salikhov K.M.: Pulse protocols for quantum computing with electron spin as qubits. Appl. Magn. Reson. 41, no. 2-4, 145-154 (2011)

14. Туранова О.А., Кальдеева Е.В., Гнездилов О.И., Никитин С.И., Туранов А.Н.: Первое мезогенное производное β-енаминокетоната дифторида бора. Журн. органической химии 80, № 2, 233-237 (2010)

15. Selivanova N.M., Galeeva A.I., Konov A.B., Gnezdilov O.I., Salikhov K.M., Galyametdinov Yu.G.: Phase diagram of the liquid crystal system of water-decanol-lantanium nitrate-decaethylene glycol monododecyl ether. Rus. J. of Phys. Chem. 84, No. 5, 802-807 (2010)

16. Mingalieva L.V., Voronkova V.K., Galeev R.T., Sukhanov A.A., Melnik S., Prodius D., Turta K.I.: EPR investigation of exchange interactions between neodymium ions in {[Nd₂((α-C₄H₃OCOO)₆(H₂O)2]}_n. Appl. Magn. Reson. 37, 737-750 (2010)

17. Krushelnitsky A., Zinkevich T., Reichert D., Chevelkov V., Reif B.: Microsecond time scale mobility in a solid protein as studied by the 15N R1ρ site-specific NMR relaxation rates. J. Am. Chem. Soc. 132(34), 11850–11853 (2010)

18. Galyautdinova A.N., Vafina R.M., Kataeva O.N., Lodochnikova O.A., Gnevashev S.G., Gnezdilov O.I., Gavrilov V.V., Shtyrlin Yu.G., Chmutova G.A., Klimovitskii E.N.: Stereochemistry of seven-membered heterocycles: XLVII. Synthesis, NMR, XRD and theoretical investigation of monosulfoxides of (Z)-4,7-dihydro-1λ⁴,3-dithiepine series. Zhurn. Org. Khim. 46, No. 2, 252-257 (2010)

19. Schmidt E.V., Ermakov V.L., Gnezdilov O.I., Matukhin V.L., Korzun B.V., Fadeeva A.A., Khabibullin I.Kh.: Structural investigation of non-stoichiometric CuInS2 by 65Cu and 115In nuclear magnetic resonance. J. of Appl. Spectroscopy 76, No. 5, 667-671 (2009)

20. Tseitlin M.P., Tseitlin O.A.: Using of digital demodulation of multiharmonic overmodulated EPR signals to improve EPR oximetry reliability. Appl. Magn. Reson. 36, 25-34 (2009)

21. Tseitlin M.P., Iyudin V.S., Tseitlin O.A.: Advantages of digital phase-sensitive detection for upgrading an obsolete CW EPR spectrometer. Appl. Magn. Reson. 35, 569-580 (2009)

22. Sukhanov A., Galeev R., Mingalieva L., Voronkova V.K., et al.: EPR investigation of the spin-spin interactions in a Cu(II)-Gd(III)-Fe(III) heterospin system. Appl. Magn. Reson. 35, 613-623 (2009)

23. Krushelnitsky A., Zinkevich T., Mukhametshina N., Tarasova N., Gogolev Y., Gnezdilov O., Fedotov V., Belton P., Reichert D.: ¹³C and ¹⁵N NMR study of hydration response of T4 lysozyme and αB-crystallin internal dynamics. J. Phys. Chem. B 113, 10022-10034 (2009)

24. Ivanshin V.A., Sukhanov A.A., Sokolov D.A., Aronson M.C., et al.: Electron spin resonance of dense Yb-based heavy-fermion compounds: New experimental data J. of Alloys and Compounds 480, 126–127 (2009)

25. Zaripov R.B., Aminova R.M., Salikhov K.M.: Application of ESEEM to study structure of free radicals. Appl. Magn. Reson. 35, 337-358 (2008)

26. Turta C.I., Chapurina L.F., Voronkova V.K., еt al.: Synthetic, spectroscopic and X-ray crystallographic structural studies on copper(II) complexes of the aminoguanizone of pyruvic acid. Inorg. Chim. Acta 361, 309-316 (2008)

27. Tseitlin M., Czechowski T., Eaton S.S., Eaton G.R.: Regularized optimization (RO) reconstruction for oximetric EPR imaging. J. Magn. Reson. 194, 212-221 (2008)

28. Ciornea V., Mingalieva L., Costes J.-P., Novitchi G., Filipova I., Galeev R., Voronkova V., Gulea A.: Structural determinations, magnetic and EPR studies of complexes involving the Cr(OH)₂Cr unit. Inorg. Chim. Acta 361, 1947-1957 (2008)